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ࡱ > S U R X 7 `i bjbjUU " 7| 7| 2 l , t iX 2 : W W W W W W W $ Y [ h 6W 6W 8? #X 8? 8? 8? ~ W 8? W 8? Z 8? E U V '2I V%
U V \ 9X 0 iX U #\ 0 #\ V 8? _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
F i _a d e s e c u r i t a t e c o n f o r m C E
D e n u m i r e c o m e r c i a l : H E L M S T A R 7 5 W G
N u m r u l p r o d u s u l u i : R . 5 4 6 . 7 5 W G . B 1 5 - 1
A c t u a l i z a r e a f i _e i : 0 8 . 0 2 . 2 0 1 1
V e r s i u n e a 3 . 0 . 0 / R O
1 . ) I d e n t i f i c a r e a s u b s t a n ce i s a u a p r e p a r a t u l u i _i a f i r m e i
I d e n t i f i c a r e a s u b s t a n ce i / p r e p a r a t u l u i
D e n u m i r e a c o m e r c i a l :
H E L M S T A R 7 5 W G
D o m e n i i d e u t i l i z a r e r e l e v a n t e i d e n t i f i c a t e _i u t i l i z r i n e r e c o m a n d a t e a l e s u b s t a n ce i s a u p r e p a r a t u l u i
D o m e n i i l e d e u t i l i z a r e r e l e v a n t e i d e n t i f i c a t e a l e s u b s t a n ce i s a u p r e p a r a t u l u i
A g e n t a u x i l i a r n a g r i c u l t u r _i h o r t i c u l t u r ; e r b i c i d
D e t a l i i p r i v i n d f u r n i z o r u l f i _e i d e s e c u r i t a t e
A d r e s a
H E L M A G
N o r d k a n a l s t r a s s e 2 8
D - 2 0 0 9 7 H a m b u r g
T e l e f o n : + 4 9 ( 0 ) 4 0 / 2 3 7 5 - 0
F a x : + 4 9 ( 0 ) 4 0 / 2 3 7 5 - 1 8 4 5
I n f o r m a ci i f u r n i z a t e p r i n t e l e f o n
T e l e f o n : + 4 9 ( 0 ) 4 0 / 2 3 7 5 - 0 F a x : + 4 9 ( 0 ) 4 0 / 2 3 7 5 - 1 8 4 5
T e l e f o n d e u r g e n c
P e n t r u s f a t u r i m e d i c a l e ( n g e r m a n _i e n g l e z )
+ 4 9 ( 0 ) 5 5 1 / 1 9 2 4 0 ( C e n t r u l d e I n f o r m a r e T o x i c o l o g i c G i f t i n f o r m a t i o n s z e n t r u m N o r d )
I n c a z d e a c c i d e n t e d e t r a n s p o r t _i a l t e u r g e n ce ( c o n s i l i e r e n g e r m a n _i e n g l e z ) :
+ 4 4 ( 0 ) 1 2 3 5 2 3 9 6 7 0 ( N C E C , N a t i o n a l C h e m i c a l E m e r g e n c y C e n t e r = C e n t r u l N a ci o n a l d e U r g e n ce C h i m i c e )
C o n s i l i e r e n l e g a t u r c u F i _a d e S e c u r i t a t e
H Y P E R L I N K " m a i l t o : S D B @ H E L M A G . C O M " S D B @ H E L M A G . C O M
2 . ) I d e n t i f i c a r e a r i s c u r i l o r
C l a s i f i c a r e a s u b s t a n ce i s a u p r e p a r a t u l u i
* C l a s i f i c a r e c o n f o r m D i r e c t i v e i 6 7 / 5 4 8 / C E E s a u 1 9 9 9 / 4 5 / C E
N ; R 5 0 / 5 3
* I n f o r m a ci i p r i v i n d c l a s i f i c a r e a
C l a s i f i c a r e a _i e t i c h e t a r e a p e b a z a r e z u l t a t e l o r o b ci n u t e n u r m a e x a m i n r i l o r t o x i c o l o g i c e
E l e m e n t e l e e t i c h e t e i
E t i c h e t a r e c o n f o r m D i r e c t i v e i 1 9 9 9 / 4 5 / C E
S i m b o l u r i d e p e r i c o l
E M B E D M S P h o t o E d . 3
P e r i c u l o s p e n t r u m e d i u
* F r a z e R
5 0 / 5 3 F o a r t e t o x i c p e n t r u o r g a n i s m e l e a c v a t i c e ; p o a t e p r o v o c a e f e c t e a d v e r s e p e t e r m e n l u n g a s u p r a m e d i u l u i a c v a t i c
* F r a z e S
6 1 E v i t a ci e l i b e r a r e a n m e d i u l a m b i a n t . C o n s u l t a ci i n s t r u c ci u n i l e s p e c i a l e / F i _a d e s e c u r i t a t e
3 . ) C o m p o z i ci e / i n f o r m a ci i p r i v i n d i n g r e d i e n t e l e
C a r a c t e r i z a r e c h i m i c
A m e s t e c c u c o n ci n u t d e 7 5 % t r i b e n u r o n - m e t i l
I n g r e d i e n t e p e r i c u l o a s e
m e t i l 2 - ( 3 - ( 4 - m e t o x i - 6 - m e t i l - 1 , 3 , 5 - t r i a z i n - 2 - y l ) 3 m e t i l u r e i d o s u l f o n i l ) b e n z o a t
N r . C E 4 0 1 - 1 9 0 - 1 N r . i n d e x 6 0 7 - 1 7 7 - 0 0 - 9 N r . C A S 1 0 1 2 0 0 - 4 8 - 0
C o n c e n t r a ci e > 7 0 < 9 0 % d i n g r e u t a t e
C l a s i f i c a r e R 4 3 N ; R 5 0 / 5 3
S i m b o l u r i d e p e r i c u l o z i t a t e X i , N F r a z e R 4 3 - 5 0 / 5 3
4 . ) M s u r i d e p r i m - a j u t o r
I n f o r m a ci i g e n e r a l e
I n d e p r t a ci i m e d i a t m b r c m i n t e a c o n t a m i n a t s a u i m p r e g n a t . T e r a p i e c u o x i g e n n c a z d e d i f i c u l t ci n r e s p i r a ci e .
D u p i n h a l a r e
S c o a t e ci p e r s o a n a l a a e r c u r a t
P a g i n a 1 ( 5 )
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
F i _a d e s e c u r i t a t e c o n f o r m C E
D e n u m i r e c o m e r c i a l : H E L M S T A R 7 5 W G
N u m r u l p r o d u s u l u i : R . 5 4 6 . 7 5 W G . B 1 5 - 1
A c t u a l i z a r e a f i _e i : 0 8 . 0 2 . 2 0 1 1
V e r s i u n e a 3 . 0 . 0 / R O
D u p c o n t a c t c u t a n a t
I n c a z d e c o n t a c t c u t a n a t , s p l a ci i m e d i a t c u a p d i n a b u n d e n c.
D u p c o n t a c t o c u l a r
I n c a z d e c o n t a c t o c u l a r , c l t i ci b i n e c u a p .
D u p i n g e r a r e
S o l i c i t a ci c o n s u l t m e d i c a l . C l t i ci b i n e g u r a c u a p . N u a d m i n i s t r a ci n i c i o d a t c e v a p e c a l e o r a l u n e i p e r s o a n e i n c o n _t i e n t e .
S f a t u r i p e n t r u m e d i c
T r a t a m e n t
S e v a t r a t a s i m p t o m a t i c .
5 . ) M s u r i d e c o m b a t e r e a i n c e n d i i l o r
M i j l o a c e a d e c v a t e d e s t i n g e r e
B i o x i d d e c a r b o n ; j e t d e a p p u l v e r i z a t ; s p u m ; e x t i n c t o r c h i m i c u s c a t
R i s c u r i d e o s e b i t e d e e x p u n e r e , p r o v e n i n d d i n s u b s t a n c s a u p r e p a r a t , p r o d u s e d e c o m b u s t i e s a u d i n g a z e l e e m a n a t e
G a z e l e p r o v e n i t e d i n a r d e r e a a c e s t u i p r o d u s s e v o r c l a s i f i c a n t o t d e a u n a c a o t r a v r e s p i r a t o r i e .
I n c a z d e i n c e n d i u p o t f i e m a n a t e u r m t o a r e l e s u b s t a n ce :
O x i z i d e a z o t ( N O x )
B i o x i d d e s u l f ( S O 2 )
E c h i p a m e n t s p e c i a l d e p r o t e c ci e p e n t r u p e r s o a n e l e c a r e i n t e r v i n n c a z d e i n c e n d i u
O p e r a ci u n i l e d e s t i n g e r e , d e s a l v a r e _i d e c u r ci r e , s u b e f e c t u l g a z e l o r d e c o m b u s t i e _i a r d e r i i m o c n i t e , s e p o t e f e c t u a n u m a i c u e c h i p a m e n t r e s p i r a t o r .
A l t e i n f o r m a ci i
R e z i d u u r i l e d e a r d e r e _i a p a c o n t a m i n a t c a r e a f o s t f o l o s i t p e n t r u s t i n g e r e a i n c e n d i u l u i s e v o r e l i m i n a c o n f o r m r e g l e m e n t r i l o r l o c a l e .
6 . ) M s u r i n c a z d e s c u r g e r i a c c i d e n t a l e
P r e c a u ci u n i p r i v i n d p e r s o a n e l e
F o l o s i ci e c h i p a m e n t u l i n d i v i d u a l d e p r o t e c ci e . A s i g u r a ci o a e r i s i r e c o r e s p u n z t o a r e . I n d e p r t a ci p e r s o a n e l e n t r - u n l o c s i g u r .
P r e c a u ci u n i p r i v i n d m e d i u l
N u a r u n c a ci n c a n a l e , a p e d e s u p r a f a c s a u n p n z e l e f r e a t i c e . N u a r u n c a ci p e s o l s a u s u b s o l .
M e t o d e d e c u r ci r e / n e u t r a l i z a r e
C o l e c t a ci p e c a l e m e c a n i c . E v i t a ci r i d i c a r e a p r a f u l u i . C o l e c t a ci n r e c i p i e n t e a d e c v a t e p e n t r u r e c u p e r a r e s a u e l i m i n a r e . I n d e p r t a ci r e z i d u u r i l e c u a p .
7 . ) M a n i p u l a r e _i d e p o z i t a r e
M a n i p u l a r e
S f a t u r i d e m a n i p u l a r e n c o n d i ci i d e s i g u r a n c
N u s u n t n e c e s a r e m s u r i s p e c i a l e , d a c p r o d u s u l e s t e d e p o z i t a t _i m a n i p u l a t c o n f o r m i n s t r u c ci u n i l o r . E v i t a ci f o r m a r e a _i d e p u n e r e a p r a f u l u i . A s i g u r a ci o b u n v e n t i l a ci e a z o n e i d e l u c r u ( l a n e v o i e a e r i s i ci c o m p l e t s p a ci u l )
S f a t u r i p r i v i n d p r e v e n i r e a i n c e n d i i l o r _i a e x p l o z i i l o r
I n c o m b i n a ci e c u a e r u l , p r a f u l p o a t e f o r m a u n a m e s t e c e x p l o z i b i l . L u a ci m s u r i p r e v e n t i v e c o n t r a f o r m r i i s a r c i n i l o r s t a t i c e . E v i t a ci o r i c e s u r s d e c l d u r s a u d e a p r i n d e r e .
D e p o z i t a r e
A l t e i n f o r m a ci i p r i v i n d c o n d i ci i l e d e d e p o z i t a r e
D e p o z i t a ci p r o d u s u l n r e c i p i e n t e n c h i s e e r m e t i c . P r o t e j a ci m p o t r i v a e x p u n e r i i d i r e c t e l a s o a r e . D e p o z i t a ci n l o c u s c a t . P s t r a ci n l o c r c o r o s . T e m p e r a t u r a d e d e p o z i t a r e r e c o m a n d a t : 2 0 C
8 . ) C o n t r o l u l e x p u n e r i i _i p r o t e c ci a p e r s o a n e l o r
V a l o r i l i m i t d e e x p u n e r e
- N i c i u n a -
E c h i p a m e n t d e p r o t e c ci e p e r s o n a l
P r o t e c ci e r e s p i r a t o r i e
P e t e r m e n s c u r t : e c h i p a m e n t d e f i l t r a r e , F i l t r u P 2 ; n c a z u l n c a r e s - a d e g a j a t p r a f , p u r t a ci m a s c d e p r o t e c ci e m p o t r i v a p u l b e r i i f i n e .
P r o t e c ci a m i n i l o r
I n a i n t e d e u t i l i z a r e , m n u _i l e d e p r o t e c ci e t r e b u i e t e s t a t e o b l i g a t o r i u , p e n t r u a s e s t a b i l i d a c s u n t a d e c v a t e c o n d i ci i l o r d e m u n c r e s p e c t i v e ( a d i c n c e e a c e p r i v e _t e r e z i s t e n ca m e c a n i c , c o m p a t i b i l i t a t e a c u p r o d u s u l _i p r o p r i e t ci l e a n t i s t a t i c e ) . V e d e ci i n s t r u c ci u n i l e _i i n f o r m a ci i l e f u r n i z a t e d e p r o d u c t o r p r i v i n d f o l o s i r e a , p s t r a r e a , n g r i j i r e a _i n l o c u i r e a m n u _i l o r d e p r o t e c ci e . M n u _i l e d e p r o t e c ci e t r e b u i e n l o c u i t e i m e d i a t d a c s e s t r i c s a u s e u z e a z . P l a n i f i c a ci o p e r a ci u n i l e n a _a f e l n c t s e v i t a ci p u r t a r e a p e r m a n e n t a m n u _i l o r d e p r o t e c ci e .
P a g i n a 2 ( 5 )
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
F i _a d e s e c u r i t a t e c o n f o r m C E
D e n u m i r e c o m e r c i a l : H E L M S T A R 7 5 W G
N u m r u l p r o d u s u l u i : R . 5 4 6 . 7 5 W G . B 1 5 - 1
A c t u a l i z a r e a f i _e i : 0 8 . 0 2 . 2 0 1 1
V e r s i u n e a 3 . 0 . 0 / R O
M a t e r i a l a d e c v a t c a u c i u c n i t r i l i c
G r o s i m e a m a t e r i a l u l u i 0 , 4 - 0 , 7 m m
T i m p d e p e n e t r a r e > 4 8 0 m i n u t e
P r o t e c ci a o c h i l o r
O c h e l a r i d e p r o t e c ci e e t a n _i ( N E 1 6 6 )
P r o t e c ci a p i e l i i
E c h i p a m e n t u _o r d e p r o t e c ci e
M s u r i g e n e r a l e d e p r o t e c ci e _i i g i e n
E v i t a ci c o n t a c t u l c u o c h i i _i p i e l e a . N u i n h a l a ci p r a f u l . S p l a ci - v p e m i n i n a i n t e d e p a u z e _i l a t e r m i n a r e a l u c r u l u i .
9 . ) P r o p r i e t ci f i z i c e _i c h i m i c e
I n f o r m a ci i g e n e r a l e
A s p e c t : g r a n u l e
C u l o a r e a l b i c i o a s
M i r o s i n s i p i d
I n f o r m a ci i i m p o r t a n t e p r i v i n d s n t a t e a , s i g u r a n ca _i m e d i u l
S c h i m b a r e a s t r i i f i z i c e
T i p P u n c t d e t o p i r e
V a l o a r e 1 4 1 C
S u b s t a n ca d e r e f e r i n c T r i b e n u r o n - m e t i l
D e n s i t a t e
V a l o a r e 0 , 6 8 g / m l
M e t o d C I P A C M T 1 5 . 1
V a l o a r e p H
V a l o a r e 7 , 6
M e t o d C I P A C M T 7 5
C o e f i c i e n t d e d i s t r i b u ci e o c t a n o l / a p ( l o g P o w )
V a l o a r e 0 , 3 9
S u b s t a n ca d e r e f e r i n c T r i b e n u r o n - m e t i l
1 0 . ) S t a b i l i t a t e _i r e a c t i v i t a t e
P r o d u s e d e d e s c o m p u n e r e p e r i c u l o a s e
N u s e c u n o s c p r o d u s e d e d e s c o m p u n e r e p e r i c u l o a s e
D e s c o m p u n e r e t e r m i c
O b s e r v a ci e N u s e d e s c o m p u n e n c a z u l u t i l i z r i i c o n f o r m i n s t r u c ci u n i l o r .
1 1 . ) I n f o r m a ci i t o x i c o l o g i c e
T o x i c i t a t e a c u t
T o x i c i t a t e a c u t o r a l
L D 5 0 > 2 0 0 0 - 5 0 0 0 m g / k g
S p e c i e _o b o l a n
M e t o d O E C D 4 2 3
T o x i c i t a t e a c u t d e r m a l
L D 5 0 > 2 0 0 0 m g / k g
S p e c i e _o b o l a n
M e t o d O E C D 4 0 2
T o x i c i t a t e a c u t l a i n h a l a r e
L D 5 0 > 6 m g / l
S p e c i e _o b o l a n
M e t o d O E C D 4 0 3
E f e c t e i r i t a n t e / c o r o z i v e
E f e c t i r i t a n t a s u p r a p i e l i i
S p e c i e i e p u r e
E v a l u a r e n u e s t e i r i t a n t
M e t o d O E C D 4 0 4
E f e c t i r i t a n t a s u p r a o c h i l o r
S p e c i e i e p u r e
E v a l u a r e i r i t a b i l i t a t e r e d u s n u e s t e n e c e s a r e t i c h e t a r e a
M e t o d O E C D 4 0 5
S e n s i b i l i z a r e
S p e c i e c o b a i
P a g i n a 3 ( 5 )
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
F i _a d e s e c u r i t a t e c o n f o r m C E
D e n u m i r e c o m e r c i a l : H E L M S T A R 7 5 W G
N u m r u l p r o d u s u l u i : R . 5 4 6 . 7 5 W G . B 1 5 - 1
A c t u a l i z a r e a f i _e i : 0 8 . 0 2 . 2 0 1 1
V e r s i u n e a 3 . 0 . 0 / R O
E v a l u a r e n u s e n s i b i l i z e a z
M e t o d O E C D 4 0 6
E f e c t e d u p e x p u n e r e r e p e t a t s a u p r e l u n g i t ( s u b a c u t , s u b c r o n i c , c r o n i c )
M u t a g e n i t a t e
N u p r e z i n t r i s c p o t e n ci a l g e n o t o x i c .
T o x i c i t a t e l a r e p r o d u c e r e
N u s - a u s e m n a l a t e f e c t e s e m n i f i c a t i v e l a r e p r o d u c e r e a _o b o l a n i l o r .
E f e c t e c a n c e r i g e n e
N u p r e z i n t r i s c p o t e n ci a l c a n c e r i g e n .
1 2 . ) I n f o r m a ci i e c o l o g i c e
E c o t o x i c i t a t e
T o x i c i t a t e l a p e _t i
L C 5 0 > 1 0 0 m g / l
S p e c i e p s t r v c u r c u b e u
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p e n t r u m e d i u S i m b o l u l p e _t e _i c o p a c
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R e s p o n s a b i l c u r e d a c t a r e a f i _e i d e s e c u r i t a t e a p r o d u s u l u i : U M C O U m w e l t C o n s u l t G m b H D - 2 1 1 0 7 H a m b u r g , G e o r g - W i l h e l m - S t r a s s e 1 8 3 b , T e l . : + 4 9 ( 4 0 ) 4 1 9 2 1 3 0 0 , F a x : + 4 9 ( 4 0 ) 4 1 9 2 3 7 8 , e - m a i l : H Y P E R L I N K " m a i l t o : u m c o @ u m c o . d e " u m c o @ u m c o . d e .
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D i r e c t i v e l e C E 2 0 0 0 / 3 9 / C E , 2 0 0 6 / 1 5 / C E , 2 0 0 9 / 1 6 1 / C E
L i s t e l e n a ci o n a l e p r i v i n d v a l o r i l e l i m i t - p r a g a l e f i e c r e i cr i , c u m o d i f i c r i l e c o r e s p u n z t o a r e
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S u r s e l e f o l o s i t e p e n t r u d e t e r m i n a r e a d a t e l o r f i z i c e , t o x i c e _i e c o t o x i c e s u n t i n d i c a t e d i r e c t n f i e c a r e c a p i t o l
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